Tetra-μ-benzoato-bis[(6-methylquinoline)copper(II)]
نویسندگان
چکیده
In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex is constructed by four bridging benzoate groups and two terminal 6-methyl-quinoline ligands. The asymmetric unit contains one-half of the whole mol-ecule, and there is an inversion center at the mid-point of the Cu⋯Cu bond. The octa-hedral coordination of each Cu atom, with four O atoms in the equatorial plane, is completed by the N atom of the 6-methyl-quinoline mol-ecule [Cu-N = 2.212 (2) Å] and by another Cu atom [Cu⋯Cu = 2.6939 (13) Å]. The Cu atom lies 0.234 Å out of the plane of the four O atoms. The molecular packing is stabilized by one intramolecular C-H⋯O as well as C-H⋯π and π-π interactions.
منابع مشابه
Tetra-μ-benzoato-bis[(quinoxaline)copper(II)]
The paddlewheel-type centrosymmetric dinuclear title complex, [Cu(2)(C(7)H(5)O(2))(4)(C(8)H(6)N(2))(2)], contains four bridging benzoate groups and two terminal quinoxaline ligands. The octa-hedral coordination around each Cu atom, with four O atoms in the equatorial plane, is completed by an N atom of a quinoxaline mol-ecule [Cu-N = 2.2465 (18) Å] and by the second Cu atom [Cu⋯Cu = 2.668 (5) Å...
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